My top 3 paints, ranked in order of how good they are.
1. MRP-Straight to airbrush. No thinning. Rock hard cure in less than 1 hour. Extremely durable.
2. Testors Enamels. Thin with their thinner if returning to the bottle. Thin with any mineral spirits brand or lacquer thinner brand if not returning to the bottle ("might" cause adverse reactions with the rest of the paint in the bottle). Curing time? An eternity...more than 7 days usually, or longer, but has a durable finish once cured.
3. Tamiya Acrylic. Thin with their thinner if returning to the bottle. Thin with 99% isopropyl alcohol (which is what I use) or lacquer thinner brand if not returning to the bottle ("might" cause adverse reactions with the rest of the paint in the bottle). Most cure in about 24 hours, a few never seem to quite cure (gloss red and gloss blue to name a couple). Durability isn't all that great, even when fully cured. Not to mention that their Model Master Gloss enamels for cars produce an unbelievably good, mirror smooth finish.
None of the above paints "go bad" (what are those paints? Are they bottles of paint, or cartons of milk?). Never once got a "bad bottle" of any of them, no matter how old they are (some of my Model Master bottles are over 30 years old), or how cold/hot they got. None require a chemistry set or precise ratios to make them do what they're supposed to do. I just thin the ones that need thinning with one thinner, and get them to the consistency of skim milk in general (usually a 50/50 mix...sometimes less...sometimes more). I don't think I have ever gotten a good bottle of Vallejo Model Air, their durability is awful, and their FS colors aren't even close (just my personal experience with them). Their Model Color, on the other hand, is one of the best I have used for brush painting...but good old Testors square bottles are still the champion there.
As you can see, there is a wide array of experiences and preferences. I just tend to move on quickly from things that you have to mess with. I figure, why do that when there are so many better options out there?