Spray the entire wheel flat black. Next, "dot-in" the wheel color (front and back) using a very fine setting on your airbrush; make sure you let a little of the black show through subtly. After it dries, apply a black or dark brown wash. In addition to picking out details, the wash will also eliminate any minor overspray from the "dotting-in" technique. Drybrush and you're done.
Gip Winecoff