The pictures I have seen also look like dull metal- aluminum I would guess. Appearance would depend on the alloy used. I think most flying boats did paint bottom. But where they stop depended on plane and airline. I have done one 314 (the Airfix kit but plan to do the Minicraft also), and added some flat grey to Testors aluminum.
There are chemical conversion processes that still retain aluminum color, but tint or darken it. Don't know if Boeing used that or not.