I can't say I've ever heard of paint thinner "going off".
Personally. I'd use the paint manufacturer's thinner exclusively for thinning the paint and use a compatible cheaper substitute for brush cleaning.
Say for example, you are using an enamel paint, use the manufacturer's thinner only for the paint and use sometihng like mineral spirits to clean your brushes.
Likewise, if using an acrylic, only use the manufacturer's thinner for the paint and wash your brushes with water (or when something a little stronger is required to clean your brushes, denatured or isopropyl alcohol)
Don't even think about thinning your paint with the same thinner you're using to clean your brushes.