My methods are much the same as Gameras. Only some slight differences:
I take my decals after cutting them out, hold them with my tweezers, and dip them in water. Afterwards, I place them on a folded paper towel to absorb excess water. I apply the blue (Set) in a small puddle on the kit. It is mostly a wetting agent that will also slightly soften the decal.
It's after it's in place do I apply the red (Sol). It softens the decal and allows it to fully conform to the surface. It will also draw it down into panel lines and conform to other details. It can be repeated to get stubborn decals to settle into place on complicated surfaces. It's much more aggressive than the blue.
Some warnings:
Not all decals are created equal! Different brands react differently to the solutions. Some go down so well, it takes little effort to get them to conform. Others are thick and seem to be unaffected by the solvent (Microsol) no matter how much you apply and how much you curse and implore the Gods of Decals for mercy!
Don't overdo the red! Puddling it on the decal can over-soften it and damage it. Too much can even mar your finish.
Resist the urge to touch the decal once the red has been applied. It can be so soft, it will stick to your finger! (Don't ask how I know this!)
The main key, as Gamera said, is a smooth, glossy finish! I even go so far as to polish the surface using an old tee shirt and good old Colgate toothpaste!
I always keep the two solutions straight by thinking of the blue as being cool (Microset) and the red as being hot! (Microsol) Ouch! Burn! Sizzle! Microset for setting and Microsol for solvent.
Jim