I certainly have used it the other way around- Testors enamel over Krylon. However, primer over enamel can be another matter. The normal way to test this is to do a sample as an experiment. Paint a piece of scrap plastic with the Testors primer, then spray the Krylon white. When dry, see if there is any problem.
BTW, near the very bottom of Finescale Forums is a forum just about painting and airbrushing. This is an excellent forum for paint questions.