I've never built a PVC kit, either, but a buddy of mine does. He likes comic book/superhero subjects, and a lot of kits of those subjects come from Japan, and are in vinyl. He does fill the parts with plaster, or sometimes with crumpled newsprint or tinfoil. Filling the parts helps them retain their shape, especially since it's necessary sometimes to apply heat with a hair dryer during assembly, and to keep their shape once the figure is done.
There are PVC kits of other subjects, too, like dinosaurs or other prehistoric animals. Same thing-you fill the cavities with plaster, to hold the shape.