Since I paint outside or in an unheated garage, I find I tend to move towards armor in the cold weather since I can paint it with a brush, plus even the light weathering I do on my armor can help hide any brush strokes I leave. Some aircraft can be done this way as well depending on the type and size. 1/72 WW1 aircraft is not a problem for me.
Autos and most aircraft I prefer to have spray paint as options. I'm just breaking out my airbrush to give it another try.
Depending on how good you are with a brush, anything is a possibility. I've brush painted cars that came out fine, its just more work and I find not quite the same level of quality as even a decent rattle can paint job. Brush painting a large surface is definately a skill that needs to be developed, not just grab a brush and go. Using flat paints is a big help too, you can always put a gloss coat over it later.
Anyway I'd vote armor as the most brush friendly, just stay away from the later war German camo schemes, a nice OD or Panzer Grey would be a good start.