Hi,
For making scenery etc. you will find that a visit to a Model Railway store is well worth the effort. Recently I have been using a product from a company called Woodland Scenics, referred to as Fine Gravel, for the Concrete. When Scattered over PVA it sticks really well, to give a more realistic compact look I then use a wall paper roller to really compact it. For the Tarmac/Blacktop Hornby make a specific product for this, I use the same method as above, I have been very happy with the results I have achieved.
I have also used a DIY product for the Concrete, like a wall filler, again I was pleased with the result but found it was prone to cracking when drying out.
H