I used styrene sheet one time, it turned out pretty good. It was for a 1/72 apron/ aircraft parking area, so it was just a flat slab really.
I cut the styrene to the size and shape I wanted, then cut expansion joints into it with a razor saw. Then I got out the liquid cement, whichever brand I had handy, and started stipling the cement onto the base with an old stiff brush. This gave it some texture, but not enough for what I had in mind. So I wrapped my finger in masking tape and sort of rolled it around in the still uncured glue. After the glue fully dries, I sanded the area lightly, knocking down and evening out the surface. It gave a pretty good looking texture with minimal work.
For the color, I started with a base coat of grey, just any neutral grey that I had on hand. After it dried to the touch, I added different shades of various other greys, some mixed with a bit of yellow to give it an aged look. Note: I was using an airbrush to do this, which allowed me to apply the paint in a random, easy to control manner.
After the concrete colors were dry, I went back into the expansion joints with a dark grey, think anthricite, almost black, to represent the tar. I also went in with a .5mm pencil and drew some random cracks around the surface. After all this was finished, I sprayed a light flat coat onto it to tie it all together. It looks pretty good, but unfortunately I don't have any pictures.
HTH