Pretty much. I did interior engineering for Gulfstram for several years so I was around them. Let me try and think of as much as I can between the two:
GV does not have windscreen wipers while the GIV does.
GV has painted smooth thrust reversers while those on the GIV were polished stainless. Also, the GIV reversers had the pivot mechanism on the outside on the deflector. This produced the humps on the reversers. I guess they could be shaved off for the GV.
Late GV also had the EVS system onboard. As a result, there is a window for the system on the bottom of the radome. Actually, I don't know if any of the C-37A's had this. I know none of the current C-20's have it.
The top section of the verticle fin on a GV is larger than the GIV to hold more equipment. However, again, latter GIV's were retrofitted with a larger unit to house much of the same equipment.
Tha't all I can think of at the moment. And if you are still thinking of doing this, the extra fuselage length of a GV is added between the windscreen and the airstair door.
Hope this helps.
Dana