PVA glue (wood glue) would work great with Styrofoam and any wooden bits. If you use plaster of Paris or similar thing, add a good dose of PVA glue to your mix, it will make your dried plaster that much restistant to chocks... Anybits that stick out of your diorama should really be ready at the time you add the fresh plaster to your base, so that they can easily be included. Failing that, you might end up with odd-looking stuff. Use PVA glue to secure those bits into the fresh plaster. Oh, also, to ease the painting of your soil, add some acrylic or water based brown paint to the mix too. I use artist kind of paints in tubes rather than 'normal' modeling acrylics (WAY cheaper!). You should find that stuff in any art/craft store.