As Moses points out, it depends on what type of paint scratching you are trying to simulate.
For German vehicles with the dark yellow basecoat, I make the scratches using MM Rust as that is the closest thing I've found to the Red Oxide primer used on vehicles for the time period. My tool for application is pretty basic...it's a round pointed toothpick dipped into slightly thinned paint and "tapped" or in some cases, lightly dragged, around the areas I want the scratches to appear. This is done before any washes or weathering otherwise the scratches stand out too much as opposed to blending in under a light coat of dust or grime. Haven't tried to scratch up a dark colored vehicle yet, but find out what the underlying primer color would have been and use that or a variation of the same color as Mo suggests.
Here's an example of what I mean:
I'm not sure these effects can be replicated with an airbrush. If someone is able to do it that way it would be interesting to hear about it.