As mentioned, Scale Auto is a good place to start.
In regards to car modelling, here are a few tips:
1) The fundamentals don't change, no matter what you build. Always read the instructions first and familiarize yourself with the parts before you break out the glue. Take the same care with mold lines and sprue attacment points as you would with an armor or airplane model.
2) You may not be used to working with vinyl or rubber tires, which most car kits use. A helpful tip is to sand the tread surface of the tire to knock the shine off and give it a realistic look. Also be aware that enamels will not cure on vinyl, if you need to paint the tires (sidewalls, lettering, etc.) use acrylics.
3) Cars have a glossy finish (if you're modelling a new one, or a show car). The advice above regarding paint and polishing materials is good. Surface prep is key - make sure you remove all mold lines, ejector-pin marks, sink marks, etc from the body before you paint it. The smoother the surface, the smoother the final color coat will be.
4) Clear parts - you may be somewhat familiar with them from building aircraft, but they're a big part of car modelling. They are very brittle, so have care removing them from the trees; it's easy to get careless and crack a window. Use white glue or epoxy to glue them in place, as these two adhesives dry clear. Plastic cement can leave nasty marks, and super-glue fumes will fog up the parts (this also happens to chrome plated parts).
5) Bare-metal foil is a gift from God. Nothing else simulates chrome trim or window surrounds better.
6) Cars are easiest to build in sub-assemblies. I usually complete the body, engine, chassis and interior, then combine these during final assembly.
7) Rear view mirrors are my bugaboo. I'm always forgetting to paint them! Then when I do try and add them on, they break. Add a small length of wire to the mirror post and drill a hole where the mirror mounts to the body for a positive attachment point and added strength. Do this before painting if the mirrors are the same color as the body.
8) Paint the body pieces at the same time to ensure uniformity of color.
Lastly, if you are not proficient or interested in detailing, don't obsess over it! You can build a nice-looking model car right out of the box with care.
Oh, and have fun!