What's your paint of preference? There's probably hundreds of good threads on the subject here, so you might do a search on it, but if everyone else is like me, they're happy to talk about their techniques.
Oils are my preference, so I can really only talk with authority about painting with oils. There are others who are handy with acrylics and would be of more help there. The process for painting with enamels is much like with acrylics, but most who could be considered very good use either oils or acrylics. Bill Horan is the only guy I know of who can get first rate results with enamels.