RTV can be de-aired in a vacuum till the material cures.... The few times that I have seen RTV stop bubbling in a vacuum, was when it was a very small pour, or it was heavily thinned. The thinned RTV is subject to shrinkage. I typically don't de-air for more than seven minutes.
A concern I have with mold making under pressure, is that if there is an air bubble near the part surface it will be compressed to it's smallest possible size at, say, 45 psi. The air bubble is not gone it is compressed. So when you release the chamber pressure, you now have an air bubble sealed in the rubber that will want to expand. It does this each time it is put under pressure and brought back to normal atmospheric pressure. This will tend to be a weak spot in the mold. It may also be why you had a tear so early in the mold life.
I use a spray mold release, Pol-EaseĀ® 2300 Mold Release, available from Tap Plastics.
Tap Plastics
I used to use their polyurethane "Quick Cast", but they recently began selling a different fromula, and the viscoscity is thicker than I prefer to work with.
On some wider flat surfaces, the mold release can often be seen on the surface of the casting. Because the mold release is supposed to create a "barrier" to help release the part, it often prevents the casting material from actually contacting the mold. This is in micro millimeter distances, but it is evidant by micro bubbles on the cast part's surface, or what sometimes looks like "water stain". The talcum powder wicks the casting material right up to the mold surface and prevents the micro bubbles or "stain" from occuring.
A simple way to help remove bubbles from your casting material is to draw it up in a seringe. The bubbles will all be up at the top of the seringe, and you "inject" the casting material and not the air. Air that is trapped in the mold while pouring, is problematic, and is best dealt with by properly designing the mold to not trap air in the first place. Proper "plumbing" is essential to a bubbleless casting. Parts molded at angles rather than flat, undercuts (parts) turned upside down, sprues at the low end for material pouring, and vent(s) at the high end for air release. Mold keys to align the mold halves, and "dams" to prevent the mold from leaking during a pour.
There is a pretty big learning curve, but by attempting your own castings at all, you are well ahead of the game.