Smooth-On (Smooth-on.com) makes multiple products for resin molding & casting. Check their website. On it there is a series of video tutorials including one, How to start resin casting and live to tell about it.
Check too their distributor list for one near you. I have one nearby and I can buy over the counter. They are also helpful in answering my questions
They offer a starter kit which includes OOMOO-30, a 30 Shore weight RTV, and a 5 minute white resin. Also included are some spritz bottles of mold release. Regarding Shore weight the higher the number the stiffer the RTV. Shore 60 is too stiff for resin but may work well for concrete. Shore 20 is too flimsy. 30 is a good compromise IMO.
Smooth On is 1:1 volume mix so you don’t need to mess with weights or smaller volumes.