Sounds like you got air trapped in the mold.
There are a variety of reasons that can affect your casting.
1.) Parts layout in the mold and the casting channels and "breather" channels by which air escapes. You will need to take undercuts into account of course.
2.) Resin has too short a setting time, resin comes in different hardening times 2 min, 5 min, 10 min, etc. This can also be affected by wrong catalyst/resin ratio(try for 1:1 Resin).
3.) Air trapped in the resin itself due to too rapid mixing or wrong stirring method.
4.) Pouring the Resin into the mold too quickly thus causing air to be trapped inside.
Always pour the resin along a stick into the mold.
5.) Not enough shaking/knocking of the mold while the resin hardens to get the extra air out.
Most professional casters use a variety of techniques/methods that are not available to use home casters.
1.) Vacuum chambers that will suck the air out of the liquid resin. Remember those old glass domes from science glass to create a vacuum.
2.) Spin casters this will spin the mold and force the resin into the mold and the air out of it. Rotor casters are used to make hollow castings to save Resin.
3.) Shaker table, the filled mold is strapped onto this and shacken/knocked.
Either way most molds will need a few "repairs" in order to get a good cast and all the air-bubbles out of it.
Here is a small hint for making the molds itself.
If you got an old mold, cut it up into small pieces and use those to add to the volume of the old. i.e. add new silicone till the part is covered and than make the mold walls from the old mold pieces and new silicone. Quiet a saving, a shop close to me lets me have old molds off-cuts for FREE.
If you can send me a pic of the mold and a casted part I might be able to give you more concrete ideas.
HTH.