Try drops of super glue on waxed paper. I remember seeing this tip somewhere, sometime ago. Put a piece of manageable-sized waxed paper on your work surface then hold a bottle of THIN ca glue ( bottle must have the small, tapered tip ) over the paper. Experiment with different sized drops to get the head size you need. The drops will ball up on the wax and dry in the domed shape of a rivet or carriage bolt.
For hex heads--- take an Allen wrench in the size you need and squeeze a piece of modeling clay ( or Silly Puddy ) around it then slowly pull the wrench out of the clay---leaving its shape in the material. Stand the clay on the waxed paper with the hole in the verticle position. Then fill the hole with thin CA glue and let it set. If you're impatient, squirt it with some Insta-set. Peel the clay away from the stick of hardened glue, then you're ready to start cutting little bolt heads from the end. To keep the little bits from flying off, lay the stick on a piece of adhesive tape that has the sticky side up. An alternative operation is to press little hex-shaped dimples in the clay and fill each of those with CA. to make individual bolt heads.
To keep the clay from clinging to the wrench when you pull it out, rub the wrench with some WD40, some patrolium jelly, PAM, or any other light oil.
To attach the heads, use a spot of clear enamel ( or clear lacquer or Future, etc. ) This would give you the " working time " to position the heads just right.
I'd suggest leaving the model alone for at least 24 hours to alow the enamel to dry completely---48 hours would probably be even better.
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