Tacobuff,
Propellant cans are ok at a pinch, but...
If you're just starting out with an airbrush, it may take two to three cans of the stuff to get a feel for your airbrush and figure things out, like how thin to make your paint, how to set your airbrush to get different effects etc. etc.
The really restrictive thing about propellant cans are that it's near impossible to make fine adjustments to your air pressure. For fine detail work, you will need to be able to back the air pressure down, something that you can't really do with the propel cans. It's somewhat analagous to trying to water seedlings with a fire hose.
Another thing about propel cans is that the pressure drops as soon as you start using it. A propel can works because the liqiud form of the propellant has a very low boiling point (much lower than room temp). As gas is released from the can, it draws heat away from it. As the temperature of the can decreases it becomes more difficult for the gas to "boil" out of the liqufied propellant. Eventually it will drop far enough that your airbrush won't pick up paint. At this point, your air can will be very cold, covered with a layer of condensation or frost.
How long does this take to happen? As little as three minutes of continuous use.
You will then have to wait for the can to return to ambient temperature before you can proceed. You can speed this up by standing the can in a basin of warm (NOT hot) water.
Knowing that you have a limited working time may tempt you to try to work fast to beat the "timeout" - this doesn't help the situation.
You will make mistakes, you will miss spots, you will get frustrated.
The moment you hook up your airbrush to a compressor, dial back the pressure and turn it on, I guarantee you will be grinning and saying to yourself "wow - this is what airbrushing is all about".
As for other tips, I'll add this one:
Multiple thin coats are much better than single thick coats.
The one pass, haul *** rule does not apply to airbrushing.
Models are three dimensional structures. There are recesses, protruberances and changes in angles and radiuses. An airbrush directs a stream of paint from a single direction - if the stream of paint encounters a solid object, it stops, simple as that.
So you must remember to fill in areas where the paint hasn't reached. I've seen examples where simple things as small as handles or raised hinges have blank areas behind them where they have "masked" a second colour of a camo scheme.
Most important of all, practice.