I've got jars/tins of Testors, Humbrol & Pactra paints that date back to the late 60s, early 70s that are perfectly usable. Probably the biggest thing that I do to ensure they remain usuable is carefully clean the top of the jar and the inside of the lid after I've used them. I simply wipe down those areas w/a rag that has been dampened with thinner and then store them in an upright position.
Salvaging paint that has started to go bad is a 50-50 proposition. If a jar/tin/can of paint sits for a period of time, the solids will precipitate out of the mixture and settle to the bottom (and thats true of any paint). After a period of time, if the paint is not mixed, a layer of hardened translucent material will form between the solids and the liquids. If the layer is thin when you discover it, you usually can salvage it - simply add a little thinner (lacquer thinner seems to work best), break up the surface as best you can with your stiring stick/rod, and then stir well. If you have lumps, you'e going to have to strain the paint - some material from a set of panty hose works very well as a strainer (ask your wife or mom for the next set she's going to throw out or if push comes to shove, visit the Dollar General and buy a pair). Simply (right!) pour the paint through the material into a new bottle. Note: the surface will often continue to thicken untill it gets to be about 3/32 to 1/8 inch thick. My rule of thumb is if the layer is 1/32 to 1/16 thick, I'll try to salvage it - any thicker and I simply throw the bottle away.
Suggestion: I've noticed that I have a few older paint colors that are no longer available that I tend to use more than others (Pactras Hot Rod Primer & Humbrols Doped Linen come to mind). I have started to make provisions so I will always have a source of those colors when the origionals run out - I paint a 1" swath of the origional color on a 3x5 file card, marking the card with the paint manufacturer, the color and the stock number and store it. When the origional runs out, I'll mix a new batch out of current available paint and then add a 1" square of that to the card, putting the mixture on the back.
Sorry to get so long winded