I've been a proponent of using baking soda for a number of different applications, from texturing non-skid, rust textures, and applique' mud, to using it overall on top of white-painted Celluclay and plaster for snow... I've never had any issues with this, never a chemical reaction that destoyed the paint, whilst some others have horror stories to tell about it...
Myself, I use Model Master and Testor's enamels, Tamiya acrylics, and various oils, temperas, and off-the-shelf spray enamels and clear laquers & acryilic varnishes...
I know that baking soda will react with vinegar, and I use vinegar as decal setting solution, although I don't think I ever applied any decals over baking soda...
Granted, I don't keep my models forever... In fact, the majority of them (unless they were are SUPER expensive) get torn down within three years, some don't last a year before they get junked and parted out, so I don't know what the long-run will be... But I don't think it's a bad idea to use baking soda as a weathering tool... Your thoughts and horror stories, please...
Jump in there, Doog..