Air pressure doesn't relate to scale, it's the brush's ability to pickup the paint. I use a Badger 100LG, which is analagous to the Infinity, and I use between 12 to 15 psi.
My normal working distance is anywhere from 1/4" to 4" and it all depends on the area I'm painting. Average will be 1 1/2" - 2".
The differences between the needles is a matter of line thickness, the thinner the needle the thinner the line and it all depends on the operator more than the needle! I rarely think about using anything other than the medium needle in my Badger.
I don't think UK version has Ammonia, which is the vital and important ingredient. See if you can find a brand (I use one called ZEP) that has Ammonia. Failing that you can probably buy some and add it into your existing brand, about 5% will do.