At 5 parts Tamiya thinner to one part paint, I'd expect you to be getting beading and poor adhesion. I wouldn't push Tamiya thinner past about 2 parts thinner to 1 part paint. I do like my paint thin, but at those rates, I prefer using denatured (ethyl) alcohol, which is "wetter" than Tamiya thinner.
If you're getting continuous spattering, without seeing it, and assuming your needle is clean and you're using an appropriate air pressure (say about 22 PSI) I would be thinking you may have a build up of paint inside the bore of the nozzle. Remove the nozzle and give it a soak in lacquer thinner and then try it again.