Seconding Stage_Left's suggestion of checking out the NMF Group Build. Lots of different approaches going on there.
Personally, I've used MM Metalizer, Talon, SnJ, and Alclad, and of the four, I like Alclad the best.
MM Metalizer is pretty fragile and vulnerable to tape lift-off.
SnJ and Talon will both give you plenty of high shine if you invest in the polishing powders and buff them in good with a dremel and a cotton wheel. Just my personal experience, but I have a heck of a time airbrushing these. Neither seems to spray well in the light, misting coats recommended, and don't really flow consistently until I pull the trigger back to about 3/4 throttle, at which point they come in a torrent. This is with an Iwata HP-C Plus and an Iwata Eclipse HP-CS with the .35mm nozzle. Haven't tried it yet with the .5mm setup, which may work better.
The cowl rings on this La-5 were done with Talon Aluminum and aluminum polishing powder:
And the bottom of this P-47 is SnJ aluminum, before and after polishing powder:
My biggest problem with both - aside from the spray issues I seem to keep having - is the mess that the polishing powders and the dremel make. Not only getting the powder everywhere, but little fibers coming off the wheel. But maybe my wheel just isn't properly "broken in".
Alclad definitely requires the most prep work up front. A smooth, high-gloss base is critical, and if you're using one of the high-shine shades (polished and airframe aluminum, chrome, stainless steel, etc), you'll need a gloss black base. I've had great luck with Tamiya X-1. I've tried the decanted Krylon technique and just don't like it as much. But to each their own.
This prop hub was painted with Alclad Airframe Aluminum. And the exhaust plates on the La-5 above were done with Dark Aluminum (I tried steel at first, but it was almost black it was so dark)...
I highly recommend experimenting...do a build or three with each technique and find the one that works for you. So much of this hobby is preference, and there's usually never one right way to do anything.