This brand really prefers a primer, eg I really like their Poly-eurethane primer available in lots of military colours, info here: http://www.acrylicosvallejo.com/gb/primers-gb.html
read up about ModeAIR & ModelCOLOR on their website.
These are sprayed un-thinned & at a higher pressure than normal & go down really well.
With Vallejo, start low air pressure & then turn it up a bit.
I find that with Vallejo AIR, i thin a little, & Model COLOR, thin a lot.
Then it's a combination of air pressure, viscosity (of paint), brand of thinner, distance from target, if target has been primed, humidity, heat, brand of air-brush, nozzle size, (0.5mm works better for me with acrylics) & what combination worked yesterday MIGHT not work today!
Ther above might just be me, & your milage may vary...
There a few (!) tutorials on you tube, search & learn, don't expect to do show winning stuff first time out.... but most importantly, experiment & learn... & have fun!