Their X-marked range is Glossy, the XF-marked range is flat.
Use the Glossy range if possible, makes the decaling easier.
You could in theory, to get a semi-gloss finish, by adding gloss varnish to the flat, but best avoided if poss.
(the XF-21 is used to make Gloss.... err Flat!)
You could use Hannant's Xtracrylics (if you can find them) aircraft acrylics as these are semi to glossy, depending on how you spray them.