Flat brushes are generally my preference over round unless they are really small. In that case I often use a toothpick.
So if I've loaded up the A/B for instance with Zinc green Chromate, I'll dig a half dozen WW 2 kits out and just generally gun the insides of the fuselage halves, the floor and anything else that looks like it might be right.
Ditto flat black for tires, engines, etc. Even while still on the sprue, it saves a lot of time later because I can start at the weathering stage, touch up a few cuts and be set, and if it turns out I was wrong- hey the part is primed!
As for dried up paints. I keep old paint around, but mostly for those moments when you need a drop of red at 11.00 at night to do an anti-collision light. For the main colors I try to buy new paint for any model. I think spending the $ 15 or so is far better than ruining a good model 30 hours in.