MilairJunkie, thank you for your comprehensive reply. Tried the freezer for a few hours, still stuck solid but that was a great idea anyway and well worth a shot. Also, I'd not considered contamination/corrosion and I think you might be onto something there (see below)
Chris, I think I have indeed underestimated the bonding characteristics of paint. (see below) Thanks!
Bick, YES! That's where I saw that post, on Don's forum. I had tried a flat toothpick, but on re-read tried a round one per Don's suggestion (after freezing). No joy. Even tried pounding on it from the business end (since the nozzle is toast at this point anyway.
BTW, long time no chat, good to hear from you, mate!
Getting back to Milair's contanimation/corrosion and Chis' comment on bonding strength of dried paint, I have remembered that when I first stared using Vallejo, I made the classic mistake of trying to clean with windex, which I had been doing with MM acryls. Perhaps that is the gunky mess that bonded the nozzle to the end cap?
I have given up at least for now, I might try to salvage the end cap later. In the meantime, replacement parts on order from Chicago Airbrush. along with a quick disconnect I've been wanting, and the needle clamping nut I lost the other night, I just bought 1/4 of a new Evolution.
Thank you all for your help!