Philo
I have seen many videos of very serious car modelers who actually strip the toy like chrome off the plastic parts. They polish the plastic then shoot gloss black which as Don mentioned, has to be glass smooth with no roughness, Then the Alclad Chrome is sprayed on which as described on the videos produces a realistic metallic chrome finish.
I have a Heller 1930's fire truck that I want to build and I will be stripping off all the factory chromed parts and will be using the Alclad method.