Hi, Scottabe - Don's recommendations are spot on, I agree with all points. For your consideration I will offer my mostly favored paint choice, Model Master enamel. It sprays very well, easy to clean the airbrush after use, not quirky as some paints can be. Acrylics are a bit less forgiving, but really not all that difficult. As Don said, a quick cleaning after use is best, a delay can add up to a messy project.
Practicing on any hard and shiny surface is a requisite, I like printed cardboard that household products come in, and for sure you want good light on the subject. Lots of experimenting with thinner ratios, spray pressures, distance to subject, etc. will all develop your skills much faster than trying to actually paint a model, even a test kit. Try laying the paint down in parallel lines, then change direction about 45 degrees for next layer, to attain even coverage. As Don said, even try circular patterns to accomplish the same. As long as you get even coverage, the paint won't care how you do it.
Enamel is much stronger in the odor department than acrylic, so do what you can to avoid prolonged spraying in direct contact with fumes, even better try to spray in a place with airflow to the outside. A spray booth with positive exhaust fan is an excellent aid for modelers.
For acrylic paint, I favor Tamiya, I just find it very consistent from batch to batch, sprays very well, adheres positively and gives a good finish. I rarely use a gloss paint, relying more on a gloss clear coat over the flat paints. Whatever medium you do use, after use cleaning is an important consideration. Some really experienced modelers say that a quick rinse by spraying some thinner through the airbrush is all it needs, but I feel strongly that at least the head set should be removed, for thorough cleaning of the little places that paint can settle in. A well maintained Iwata or other fine brushes can deliver YEARS of trouble free use, but it doesn't take much neglect to shorten it's useful life and require a rebuild of the more critical parts.
This forum is an excellent place for asking questions and learning, feel free to fire away. Most of what I have learned came from this site and other sources. Also, if you haven't already done so, have a look at Don's Airbrush website, a quick Google check will take you there, priceless information about all things related to airbrushing. Highly recommended. Good luck as you move forward with your Iwata Neo.
Patrick