I was a "returnee" modeler too. You really should consider an airbrush, the initial cost of the brush and compressor will be born out over several years of painting enjoyment (well except when the darn thing gives you fits-sigh). That said you can brush paint models with acrylic paints but that family of paints is faster drying than enamels, so look for some "extender" (drying inhibitor)[ art /craft supply stores] to help slow down the drying time. Also the thinners you use will have an effect on the coverage and flow of the paint. So I would recommend using your paint brands own thinner, to cut down the variables a bit.
Regardless, just build models, get the paint on 'em, as you like and check out the "How to's"
http://www.finescale.com/home/videos/how%20to.aspx to get a start.
Oh and welcome back to the most fun you can have and to the forum