Second 214's post, a paint system is composed of many ingredients, solids, solvents and stabilizers. Even when purchased new off the shelf, they must be stirred completely until no thick globs of it remain on the lower part of the stick. 214 is right, when properly sealed I have had Model Master enamel store for many years, but the lid seal has to be perfect or air does it in.
I never shake the bottle, that only goobers up the lid threads and seal insert. That ensures the bottle will not seal properly again. I use a small dental spatula for initial stirring, or piece of sprue, I avoid wood, since it could introduce particle contamination. When thoroughly stirred I use a Badger mixer and give it a good blend. Then, in order to transfer to a separate bottle for thinning and further mixing, I never pour over the bottle side in order to keep the bottle threads clean. For transferring I use a syringe or even a straw, with a thumb over the end it will hold paint inside for transfer.
So the answer to the question of enamel storage, relates mostly to the condition of the bottle seal. Keep the cap and bottle threads clean and it can be stored for a very long time. If some paint should still find it's way to the outside anyway, be sure to completely clean the threads before re-capping. I'll bet if you go back to that bottle you checked, then give it a quick stir, you'll find lot's of thick material at the bottom of the stick. Hope this helps.
Patrick