The undercoat to use with Alclad metalizing finishes depends a bit on the particular shade you are using. The polished aluminum requires a very glossy black. The plain or airframe aluminum is less critical, and the white aluminum even less so.
But the polished aluminum, which needs to be done with a single, very thin coat, depends greatly on that undercoat, so it must be highly glossy, and absolutely flaw free. Enamels make for more glossy finishes, and that is why they are so popular under the polished aluminum alclad.
I have used other undercoats with the natural or white aluminum with okay results. In fact, some of use use colored undercoats some time to get a different tint for the Alclad. Best advise for trying something like that is to experiment on scrap.