Don,
There is a photo of your air valve disassembled on this page. You don't have to remove it from the airbrush. Just use a small allen wrench to unscrew the bottom. Notice the tiny O-ring. It could be worn or dirty. Don't get solvent on it. It could swell and jam.
Make sure you don't just have paint clogging the opening in the front of the airbrush or inside the spray regulator.
Don