Head on out to your local automotive paint shop. There they have some 3M vinyl tape. If you watch Bitchin Rides, Iron Resurection, or other of the custom car shows on cable. They use these tapes to set the edges on masking areas. The blue tape is 1/8, the orange is 1/4. Heck, Tamiya also maes some 1/16 tape in white.
Like Don says, set the edge of the area to be masked with the vinyl tape. Set one end and pull taut, stretching the tape slightly. Touch the opposite end down and press the tape down & burnish smooth. If you are masking a curve, touch one end down and press down the tape as you reel it off the spool -- following your line. Burnish smooth.
Backfill the area to be masked with a wider tape, Tamiya yellow, Frog Tape, or another Kabuki-type tape. 3M painters tape is also good, but really hard to get a good straight paint-free masking line without using the vinyl as the edging.