I hesitate to reply because I can't answer your question- I don't use Vallejo paints.
I would always say that white only really works over...white.
It's funny, I'm building a car model and I lie awake looking at the ceiling trying to figure out the order in which to layer colors.
There's been some statements about spray cans being for kids only, but look, white out of a spray can can't be beat. I go with Tamiya Fine White. And their gray isn't far behind.
They now majke the gray in fine and it's amazing, great for models where the finish coat is white.
Contradiction? No, that gray is like a 3 pms, really light.
BTW that Spitfire is fine looking.