stikpusher
It happened on some aircraft types. I can say about the Spitfire though. But many Japanese aircraft types, especially early war, had the front of the blade in bare metal and the back side in either black or red brown primer.
Many US planes also had metal props natural finish on front and black on rear, to reduce glare.
The red/brown color on Spitfires may have been wooden props. Some early Spits did have wooden props, but they were soon replaced after war started.