Hi;
I think that in modeling that refers to the paint after you open it. Now if you don't use it out of the bottle, Then shelf life becomes the issue. Not using it straight means a lot. Thin it and you change the viscosity and gassing out time and quality. Thin it say 50% and you've got a whole new dog in the hunt.
Unadulterated, from the bottle means the shelf life of what's left in the bottle is up to you. I am saying that if you don't clean the bottle rim and top you may not get a good re-seal. Paint not thinned, will last a long time. I've got a lot of Model Master metallics that are over ten years old.
Those were Enamels ( Oil Based),Their new stuff ( Acrylics ) Doesn't seem to want to cover by brushing. It comes out uneven and blotchy. I have had two of the acrylic colors ( Red and Green ) skin up in the bottle. And I had done the cleaning I mentioned. So Who really knows. I have found too, if you buy extra bottles to put your mixes in, Buy Glass not Plastic.
This I learned the hard way. Had some beautiful Kure Arsenal Japanese Imperial Navy Grey in ten bottles. When I went to use it it was rock solid in three of the bottles, and I used them New! T.B.