I could be wrong, Mike, but I think what he meant is that since the circle template is so large and the wheel is sunk down into the tire, that there is a space between template and wheel that allows paint to get under the template.
If that's the case, about all I can think of is as J-Hulk said. Mash it down as flat as you can and spray straight down or angled in toward the center of the wheel. Also use the lowest air pressure you can get by with.