You are never going to get it exact because the instruction pictorials are two dimensional whereas your model is three dimensional. For example, looking at the top view of the model in the instructions, there may be a camo pattern running down the side of the fuselage that looks real small but in reality, when looking at things from the side it is pretty big.
But ... to answer your question:
1) Measure the EXACT distance between two points on the instruction sheet. The wing tips are a good choice, from the back of the prop spinner to the back of the rudder is another good choice.
2) Measure the EXACT dimension between the same two points on your model. Make sure you hold your ruler, tape measure, whatever so that it doesnt bend over the top. You want to measure the horizontal distanec between the two points.
3) Divide the measurement from your moedl by the measurement from your instructions. Say your model is 14" from wing tip to wing tip and the instructions are 10" between the same two points. Divide 14 by 10 and you get 1.4 which equates to a 140% enlagement. If you have fractional inches, such as 3/16 or 7/8 or something like that, divide the top number by the bottom number to get a decimal inch. For example, 7 13 / 16 = 7 + (13 / 16) = 7.8125"