I have tried both post and pre shading, and have had NO success with either.
I think it's just me, and it being one of the things in life you simply can't get right.
So instead I make all my shading post, but using Tamiya smoke rather than any of the base colours or mixes there of.
Being translucent in appearance, you simply apply as much as you like till you get the desired effect, on panel lines layers will give a draker shade, and allow the base colour to show through, effectively tinting it in reality, and therefore higlighting the inner panels themselves.
This works well for me, and saves the mess around of multi colour camo schemes.
Mind you, for rivet counters, it may not be authentic enough.
Horses for courses really.