There's a lot of good advice, here, and I'dlike to add some:
The enemies of paint, cured or otherwise, are:
sunlight, particularly UV.
freezing and thawing (this is true for all paints, not just acrylics)
oxygen
excessive heat
incompatible solvents
contaminants.
Absent the results of poor storage practices, covered in previous posts, the shelf life of a paint depends on its formulation. A well fomumlated, modern paint can last for decades if kept in a tightly sealed container, protected from sunlight, oxygen, and excessive heat and cold.
High heat causes polymerization (partial curing) of the liquid resins (binder) in the paint. Cold effectively changes the formulation of the paint (it is actually the warming or thawing afterward that causes the problem).
UV changes the characteristics of the binder molecules, changing the way they interact with the pigment and each other.
Oxygen and incompatible solvents effectively change the formulation, possibly making it less stable.
How can you tell if old paint has gone past its usefulness? Stir it up by hand, initially. Don't use a powered stirer. If portions of the paint stay stringy or lumpy after thorough hand mixing, throw it out. If not, get out the power stirer, and mix it thoroughly, then let it stand overnight, and stir again. It should then be ready to use. It is always wise to strain or filter old paints before use.