The spray comes out of the nozzle in a cone shape. Plain old common sense says that the closer you can get to the surface the narrower the line will be. But to do that you have to balance everything else, including how far you pull the trigger back.
Everything is related. How far you can pull the trigger back without blowing paint everywhere is dependant on the pressure you are spraying at, the viscosity of your paint (how much it was thinned), and how far from the surface you are spraying.