If your power supply doesn't have an on/off switch, then turn it off at the power point.
If thats a hassle/difficult to get too, then put a switch in line with one of the power leads running to the fan.
Or cut into the power lead from the computer power supply to the wall socket, and place a junction box with a switch mounted in it, and wire your power through the switch.
Just like some desk lamps, with the on/off switch half way down the power lead.
As far as your old computer power supply wiring goes, in the 4 way connector
BLACK IS NEGATIVE 12V and
RED IS POSITIVE 12V.
An AC/DC convertor will work just fine also, but see if you can get one with a switch on the front.
Also take note of the current ratings, sometimes they slap on a big 10AMP claim, but it actually runs at 6 amps continuous.
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