hey! I am a true blue believer in Vallejo paints and it is 80% of what I spray with now. As long as you gave the enamel time to thoroughly dry first, you should be able to paint over it with acrylic. I use Krylon white enamel primer from Wal Mart on most things I prime for Vallejo, and it works great. Usually 24 to 48 hrs, leaning more to the 48 hours is time enough to be able to spray over it.
Second, what are you thinning with? Vallejo's thinner or just plain distilled water? I've used both and prefer Vallejo's thinner. It has an adhesion additive and a retarder in it... My suggestion would be to not thin that one color and try spraying it like that. You didn't mention if it was Model Color or Model Air you were spraying. That would make a difference too. (Model Air you don't need to thin) ... but it sounds like either not enough pigment and adhesive were mixed in with the paint (try mixing it longer) or it was too thin.
Hope this helps! Let us know how it works out!
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I just reread your original question and see it was being sprayed unthinned. Try giving it an extra long mixing and see if that helps. I haven't sprayed the dunkelgelb in vallejo yet, only sand yellow and middlestone along those shades. It could just be a bad bottle or not thoroughly mixed. I've noticed on a few colors (especially if they have lay dormant for awhile) if I don't really mix them good I end up with a very thin paint...