I once worked in the coatings industry, and I've worked side by side with coatings chemists for the last twenty-five years.
Properly kept and cared for, paint (enamel or acrylic) can last for decades.
From your description, it sounds as if something has ruined your paint, but from the rest of your post, it is unclear whether this occured before you opened the bottle or afterwards. Once paint turns into a "goopy mass" it is generally no longer usable. This is caused by either extreme old age or mixture with incompatible materials.
Lacquer thinner is intended for use with lacquers. It may dissolve enamels, and may be useful for cleaning some of them, but generally it should be used with lacquers.
The best and safest (for the paint) solvent for thinning and cleaning enamels is mineral spirits (generic "paint thinner" is essentially mineral spirits.)
Never keep paint that has been thinned for airbrushing for more than about a week—better if only for a few days. Absolutely never return such paint to the original container.
If that is what you did with your gray paint, and you used lacquer thinner to thin (the proper paint term is "reduce") the paint for spraying, I'm not at all surprised that it turned into unusable goo.