I have never had a problem using Poly S paints, but from personal experience, I always wash the model to get rid of any release agent, let it dry. Then I usually undercoat my models with either Humbrol number 64 grey, or Gunze Mr Surfacer 1000 spray can. Gunze also make Mr Base White spray, which is great for covering dark colours such as Black and Red plastic. This will also make the red you are trying to paint appear brighter.