David, I'm guessing that, as a guitar builder, you know how to prepare a surface for a coating. Apparently, many do not, or they do but they get careless. And to most people, paint is something they take for granted—all paints perform exactly alike, regardless of anything else, right?
Um, no.
Enamels and traditional lacquers have been around for so long that they are very well developed technologies—almost all the bugs that can arise are well known, as are the fixes. Acrylics are in their early childhood, by comparison. And they don't work the same way as enamels.
As for the bare bones of your question: poor paint adhesion is due to one or more of the following:
- Poorly formulated paint. (Not very common. Most modern model paints are at least adequately formulated. YMMV)
- Poor surface preparation. (Extremely common.)
- Using the wrong paint for the surface. (Common, but not frequent, at least in modeling.)
- Deteriorated paint. It does have a shelf life.
- Poor application. (Common.)
- Poor application conditions. (Common, but not frequent.)
- I know I've missed something………