Usually Windex is the thinner of choice for MM acrylics, since it contains both alcohol and ammonia, occasionally adding a bit of alcohol.
I never use straight 91% alcohol for anything but cleaning bristle brushes, as it will swell and ruin the "O"-Rings in a normal airbrush. But even there, fingernail polish remover is better as the glycerin keeps the bristles supple.
As for the reaction you got with the MM flat black, it looks like you mixed the alcohol with a bottle of paint that has been opened then kept for too long and developed mildew in it, which causes the solids to clump and separate as the alcohol kills the mildew that has set up in the solids thusly breaking them down.
To prevent this it is good to add a little 91% alcohol to a bottle you have opened before you store it, but not 50/50 as you did.